CHEM 418 Nuclear Chemistry, Winter 2017: Lecture 13 Neptunium Chemistry

Neptunium chemistry is covered in this lecture.  Nuclear properties and synthesis of neptunium are described, with emphasis placed on the isotopes 235-239Np.  The synthesis and properties of neptunium metal, alloys, and intermetallic compounds are introduced.  The lecture describes neptunium compound synthesis, with resulting thermodynamic and structural properties provided.  Neptunium organometallic and coordination compounds are also presented.  Information on neptunium solution speciation, redox, and spectroscopy is given, with trends based on oxidation state examined.  A presentation of analytical methods useful in neptunium chemistry, including Mössbauer spectroscopy, concludes the lecture.  Comparisons are made with uranium chemistry to provide trends in the actinides. The lecture length is 26 minutes.  The lecture is assigned on Monday 13 February 2017 and due Saturday 18 February 2017.